Efficient C-S cross coupling catalyzed by Cu2O

A protocol for the copper-catalyzed C-S bond formation between aryl, alkyl, or heteroaryl thiols and aryl or heteroaryl halides is reported. The reaction is catalyzed by Cu₂O which shows the highest catalytic activity with ethyl 2-oxocyclohexanecarboxylate ligand in DMSO at 80 °C. The corresponding coupling products are obtained with good to excellent yields under relatively mild reaction conditions with good chemoselectivity and functional group tolerance.     

Viscoplastic flow in slightly varying channels with wall slip pertaining to a magnetorheological (MR) polishing process

In this paper, the first analytical endeavor into the fluid dynamic modeling of an MR polishing process is reported. The velocity and shear stress fields of an MR fluid running through a thin slippery channel with a slightly varying height are analytically solved using a bi-viscosity constitutive model and a Navier slip model. Estimations of the mechanical power density and the total power per unit depth applied onto the channel surfaces are also presented. Analytical solutions for the Couette–Poiseuille flow behavior of a bi-viscous fluid flowing through either parallel or non-uniform channels are obtained, and the associated necessary and sufficient conditions characterizing a total of 5 types of flow are derived.The behaviors of the fluid are examined through the use of a parametric diagram of Bingham number (Bn) and Couette number (Co), i.e., Bn–Co or 1/Bn–1/Co diagram, by changing the geometric and operating conditions. Using these diagrams, variations in the rheological characteristics of the flow are investigated in great detail, with a special focus on the movement of the pseudo-core region. Finally, the mechanical power density field obtained for the flow in a converging–diverging channel is used to explain the wear mechanism in the MR polishing process. The effects of the power density field and the total power on the material removal rate (MRR) and the within-workpiece nonuniformity (WIWNU) with respect to various geometric and operating conditions are evaluated.     

On Fundamental Group of a Certain Class of Welded Knots

In this paper, a certain class of welded knots K_(2n) is considered. By calculating the commutators subgroup of fundamental group Gn of welded knot K_(2n),n ∈ Z~+, we show that these welded knots are not equivalent to each other and they are all not classical knots. Secondly, we study some properties of Gn and obtain that Gn is linear, residually finite and Hopfian.     

不对称(口片)呐醇偶联反应新进展

综述了近年来不同催化体系的不对称合成呐醇的方法,并总结了不同的催化效率和对映选择性的差异.     

A branch-and-bound algorithm of the single machine schedule with sequence-dependent setup times for minimizing maximum tardiness

This paper addresses the NP-hard problem of scheduling N jobs on a single machine with due dates, sequence-dependent setup times and no preemption where the objective is to minimize the maximum tardiness. An algorithm based on branch-and-bound permutation schemes is developed including the implementation of lower and upper bounding procedures, and three dominance rules. Computational experiments demonstrate the effectiveness of the algorithm. In the experiments, the impacts of control parameters to generate test instances on algorithm performance (CPU times) are studied by statistics methods.     

积分中值定理的推广及其应用(英文)

给出了积分中值定理的一个推广,讨论了推广的积分中值定理中间值的渐近性.     

浅析数学建模

数学建模在数学和其他学科的发展过程中具有重要的意义.数学建模有助于学生感受数学在解决实际问题中的价值和作用,体验综合运用知识和方法解决实际问题的过程;有助于激发学生学习数学的兴趣,培养学生的创新意识和实践能力.数学建模竞赛的开展有力地推动了高等院校数学教学体系、教学内容和教学方式的改革.     

一种四次有理插值样条及其逼近性质

1引言有理样条函数是多项式样条函数的一种自然推广,但由于有理样条空间的复杂性,所以有关它的研究成果不象多项式样条那样完美,许多问题还值得进一步的研究．近几十年来,有理插值样条,特别是有理三次有理插值样条,由于它们在曲线曲面设计中的应用,已有许多学者进行了深入研究,取得了一系列的成果(见[1]-[7])．但四次有理插值样条由于其构造所花费的计算量太大以及在使用上很不方便而让人们忽视了其重要的应用价值,因此很少有人研究他们．实际上,在某些情况下四次有理插值样条有其独特的应用效果,如文[8]建立的一种具有局部插值性质的分母为二次的四次有理样条,即一个剖分